https://ogma.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:10776 12. In the presence of metal(II) ions they undergo concomitant deprotonation and complexation to form [M(L-2H)] compounds. Formation constants have been determined for Cu(II), Ni(II), and Zn(II) complexes of the suite of ligands. Determined values for the two observed steps of log β ML-2H and log β ML-3H (where additional alcohol or coordinated water deprotonation occurs) are approximately −10 and −20, respectively. As pKa values of the diamide cannot be determined independently, absolute log KML-2H values for the di-deprotonated complexes cannot be definitively assigned, although estimates are made using predicted pKa values for the diamide. The circular dichroism spectra of optically active complexes were determined and are discussed.]]> Sat 24 Mar 2018 08:07:05 AEDT ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:17417 p_y) facial Co(III) complexes are presented. Protonation constants for 1 and stability constants with Cu(II), Ni(II), and Zn(II) are reported, with both ML and ML₂ species defined. The trend for ML (log K₁ values for Cu, Ni, and Zn of 8.3, 6.9, and 5.3, respectively) is conventional. Protonation and stability constants with Cu(II) for N,N-bis(2-pyridylmethyl)amine (2) were also defined. The log K₁ value measured for 2 of 7.4 is very similar to that found for 1 of 8.3, despite the marked difference in the third donor group; it appears that the third donor of the tridentate ligand generally binds only poorly to Jahn–Teller elongated Cu(II) in solution.]]> Sat 24 Mar 2018 08:01:37 AEDT ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:34246 Fri 22 Feb 2019 16:55:11 AEDT ]]>